PHYSICAL MATHEMATICS SEMINAR TOPIC: WHAT OSTEOPOROSIS AND CONCRETE EMPLOYED IN NUCLEAR WASTE STORAGE SYSTEM HAVE IN COMMON SPEAKER: FRANZ-JOSEF ULM Gilbert W. Winslow Associate Professor Department of Civil & Environmental Engineering Massachusetts Institute of Technology ABSTRACT: Osteoporosis is a skeletal disease characterized by low bone mass density (BMD) and microarchitectural deterioration of bone tissue. Recent estimations by the National Osteoporosis Foundation indicate that in 1996 approximately 29 million people aged over 50 in the United States either had osteoporosis or were at risk of developing the disease. This number is expected to be 41 million by the year 2015. In undegraded bone, a finely tuned cellular activity ensures a continuous remodeling of bone, repairing damage and fracture in the microstructure. This process is regulated by two types of cells: Resorbing cells, called osteoclasts, dissolve bone minerals (hydroxyapatite), and osteoblasts cells move into the space left by the osteoclasts, regenerating the collagenous micromorphology and the chemical boundary conditions for the re-mineralization of bone. While the biochemomechanical deterioration of bone that leads to osteoporosis is still a matter of intensive research, it seems to result from a kinematic imbalance between osteoclast and osteoblast activity. With increasing age, the overall resorption rate is higher than the overall refilling rate, and this kinematic imbalance leads ultimately to an increased risk of bone fracture during downfall. At first glance, concrete durability problems are of a different kind: they are conditioned by heat- and mass transport phenomena, amplified in time and space by chemical reactions, which are coupled with deformation and fracture of the material. A typical example is Calcium leaching of cementitious materials, which some years ago has been recognized as critical for concrete employed in nuclear waste storage systems. The leaching is caused by water intruding the storage system having a lower calcium concentration than some chemical equilibrium condition. The leaching of the Calcium from the matrix (Portlandite Crystals, C-S-H), leads to a significant loss of strength and stiffness, and the material becomes significantly pressure sensitive, which may ultimately impair the structural integrity of the storage system. On second sight, osteoporosis and Calcium leaching of concrete materials have several things in common, starting from a `bony' microstructure of Calcium leached cementitious materials, which shows strong similarity with osteoporotic bones; and progress in one field may well improve health monitoring capabilities in the other. Having this in mind, the talk reviews some recent results of research on Calcium leached cement-based material systems dealing with (1) deterioration kinetics; (2) asymptotic material behavior, and (3) monitoring by modeling the integrity of concrete structures subjected to severe chemical softening. DATE: TUESDAY, APRIL 24, 2001 TIME: 2:30 PM LOCATION: Building 2, Room 338 Refreshments will be served at 3:30 PM in Room 2-349 Massachusetts Institute of Technology Department of Mathematics Cambridge, MA 02139